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author:

Li, Hong (Li, Hong.) [1] | Wu, Bo (Wu, Bo.) [2] | Lin, Cong (Lin, Cong.) [3] (Scholars:林枞) | Wu, Xiao (Wu, Xiao.) [4] (Scholars:吴啸) | Lin, Tengfei (Lin, Tengfei.) [5] (Scholars:林腾飞) | Gao, Min (Gao, Min.) [6] (Scholars:高旻) | Tao, Hong (Tao, Hong.) [7] | Wu, Wenjuan (Wu, Wenjuan.) [8] | Zhao, Chunlin (Zhao, Chunlin.) [9] (Scholars:赵纯林)

Indexed by:

EI Scopus SCIE CSCD

Abstract:

Barium titanate [ BaTiO 3 (BT)]-based ceramics are typical ferroelectric materials. Here, the discontinuous grain growth (DGG) and relevant grain size effect are deeply studied. An obvious DGG phenomenon is observed in a paradigmatic Zr 4 + -doped BT-based ceramic, with grains growing from -2.2-6.6 to -121.8- 198.4 & mu;m discontinuously near 1320 & DEG;C. It is found that fine grains can get together and grow into large ones with liquid phase surrounding them above eutectic temperature. Then the grain boundary density ( D g ) is quantitatively studied and shows a first-order reciprocal relationship with grain size, and the grain size effect is dependent on D g . Fine grains lead to high D g , and then cause fine domains and pseudocubiclike phase structure because of the interrupted long-range ferroelectric orders by grain boundary. High D g also causes the diffusion phase transition and low Curie dielectric peak due to the distribution of phase transition temperature induced by internal stress. Local domain switching experiments reveal that the polarization orientation is more difficult near the grain boundary, implying that the grain boundary inhibition dominates the process of polarization orientation in fine-grain ceramics, which leads to low polarization but a high coercive field. However, large-grain ceramics exhibit easy domain switching and high & similar ferroelectricity. This work reveals that the grain boundary effect dominates the grain size effect in fine-grain ceramics, and expands current knowledge on DGG and grain size effect in polycrystalline materials. & COPY; 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Keyword:

BT-based ferroelectric ceramics Discontinuous grain growth Grain boundary density Grain size effect on structure Microscopic origin property

Community:

  • [ 1 ] [Li, Hong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Lin, Cong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Wu, Xiao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Lin, Tengfei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Gao, Min]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Zhao, Chunlin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Wu, Bo]Southwest Minzu Univ, Phys Dept, Chengdu 610041, Peoples R China
  • [ 8 ] [Tao, Hong]Southwest Minzu Univ, Phys Dept, Chengdu 610041, Peoples R China
  • [ 9 ] [Wu, Wenjuan]Chengdu Univ Informat Technol, Sichuan Prov Key Lab Informat Mat & Devices Applic, Chengdu 610225, Peoples R China

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Source :

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY

ISSN: 1005-0302

CN: 21-1315/TG

Year: 2023

Volume: 164

Page: 119-128

1 1 . 2

JCR@2023

1 1 . 2 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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