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author:

Li, Hong (Li, Hong.) [1] | Wu, Bo (Wu, Bo.) [2] | Lin, Cong (Lin, Cong.) [3] | Wu, Xiao (Wu, Xiao.) [4] | Lin, Tengfei (Lin, Tengfei.) [5] | Gao, Min (Gao, Min.) [6] | Tao, Hong (Tao, Hong.) [7] | Wu, Wenjuan (Wu, Wenjuan.) [8] | Zhao, Chunlin (Zhao, Chunlin.) [9]

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EI CSCD

Abstract:

Barium titanate [BaTiO3 (BT)]-based ceramics are typical ferroelectric materials. Here, the discontinuous grain growth (DGG) and relevant grain size effect are deeply studied. An obvious DGG phenomenon is observed in a paradigmatic Zr4+-doped BT-based ceramic, with grains growing from ∼2.2–6.6 to ∼121.8–198.4 μm discontinuously near 1320 . It is found that fine grains can get together and grow into large ones with liquid phase surrounding them above eutectic temperature. Then the grain boundary density (Dg) is quantitatively studied and shows a first-order reciprocal relationship with grain size, and the grain size effect is dependent on Dg. Fine grains lead to high Dg, and then cause fine domains and pseudocubic-like phase structure because of the interrupted long-range ferroelectric orders by grain boundary. High Dg also causes the diffusion phase transition and low Curie dielectric peak due to the distribution of phase transition temperature induced by internal stress. Local domain switching experiments reveal that the polarization orientation is more difficult near the grain boundary, implying that the grain boundary inhibition dominates the process of polarization orientation in fine-grain ceramics, which leads to low polarization but a high coercive field. However, large-grain ceramics exhibit easy domain switching and high & similar ferroelectricity. This work reveals that the grain boundary effect dominates the grain size effect in fine-grain ceramics, and expands current knowledge on DGG and grain size effect in polycrystalline materials. © 2023

Keyword:

Barium titanate Coercive force Ferroelectricity Ferroelectric materials Grain boundaries Grain growth Grain size and shape Polarization Polycrystalline materials Size determination

Community:

  • [ 1 ] [Li, Hong]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Wu, Bo]Physics Department, Southwest Minzu University, Chengdu, 610041, China
  • [ 3 ] [Lin, Cong]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Wu, Xiao]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Lin, Tengfei]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 6 ] [Gao, Min]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Tao, Hong]Physics Department, Southwest Minzu University, Chengdu, 610041, China
  • [ 8 ] [Wu, Wenjuan]Sichuan Province Key Laboratory of Information Materials and Devices Application, Chengdu University of Information Technology, Chengdu, 610225, China
  • [ 9 ] [Zhao, Chunlin]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China

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Source :

Journal of Materials Science and Technology

ISSN: 1005-0302

Year: 2023

Volume: 164

Page: 119-128

1 1 . 2

JCR@2023

1 1 . 2 0 0

JCR@2023

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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