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author:

Ding, Jianfeng (Ding, Jianfeng.) [1] | Tang, Cheng (Tang, Cheng.) [2] | Zhu, Guanjia (Zhu, Guanjia.) [3] | Sun, Weiwei (Sun, Weiwei.) [4] | Du, Aijun (Du, Aijun.) [5] | He, Fengyi (He, Fengyi.) [6] | Wu, Minghong (Wu, Minghong.) [7] (Scholars:吴明红) | Zhang, Haijiao (Zhang, Haijiao.) [8]

Indexed by:

SCIE

Abstract:

Transition-metal dichalcogenides with a lamellar structure have been recognized as a class of attractive host materials for Na+ insertion, and intensively investigated as anodes for sodium-ion batteries. However, large-scale applications are severely restricted by their intrinsic inferior conductivity and large volume expansion during deep cycles. Herein, a unique 0D/2D heterostructure of SnS2 quantum dots (QDs) with N-doped Ti3C2Tx MXene (namely, SnS2 QDs/Ti3C2) has been successfully designed via an ingenious solvent spatial confinement growth strategy. During the hydrothermal process, the nucleation and growth of SnS2 nanoparticles can be effectively regulated by N-methyl pyrrolidone, which results in the uniform growth of SnS2 QDs of about 3 nm onto the Ti3C2Tx MXene matrix. Meanwhile, in situ N-doping of Ti3C2Tx MXene can also be realized because of the NH3 released from the decomposition of the sulfur precursor, which greatly enhances the interfacial Na+ transport. Such a rational design endows the newly developed SnS2 QDs/Ti3C2 electrode with fascinating sodium storage properties including a high specific capacity of 763.2 mA h g(-1) at 100 mA g(-1) and ultrastable cycling stability (345.3 mA h g(-1) at 100 mA g(-1) after 600 cycles). The experimental and theoretical simulation results demonstrate that the ultrafine SnS2 QDs with abundantly active sites on the interface and stronger Na+ adsorption energy on the heterojunction formed between N-doped Ti3C2 MXenes contribute to the superior sodium storage capability.

Keyword:

confined growth in situ N-doping SnS2 quantum dots sodium storage capability Ti3C2Tx MXene

Community:

  • [ 1 ] [Ding, Jianfeng]Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 2 ] [Zhu, Guanjia]Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 3 ] [He, Fengyi]Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 4 ] [Zhang, Haijiao]Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 5 ] [Tang, Cheng]Queensland Univ Technol, Sci & Engn Fac, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia
  • [ 6 ] [Du, Aijun]Queensland Univ Technol, Sci & Engn Fac, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia
  • [ 7 ] [Sun, Weiwei]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 8 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China

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Source :

ACS APPLIED ENERGY MATERIALS

ISSN: 2574-0962

Year: 2021

Issue: 1

Volume: 4

Page: 846-854

6 . 9 5 9

JCR@2021

5 . 5 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 38

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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