Molybdenum　disulfide　(MoS2)　has　been　widely　deemed　as　an　attractive　anode　candidate　for　rechargeable　lithium　-ion　batteries　(LIBs)　on　account　of　its　apparently　high　capacity　and　intriguing　2-dimensional　layered　structure.　In　our　work,　the　growth　of　MoS2　nanoflowers　with　an　expanded　interlayer　spacing　onto　nitrogen-doped　reduced　graphene　oxide　has　been　successfully　performed　by　using　an　effective　poly(vinylpyrrolidone)　(PVP)-guided　assembly　route.　The　theoretical　and　experimental　results　indicate　that　PVP,　as　a　linker,　is　a　major　contribution,　both　in　regulating　the　microstructure　of　MoS2　nanoflowers　and　improving　the　electrochemical　properties　of　the　flower-like　MoS2/N-graphene　(F-MoS2/NG)　composite.　When　utilized　as　anode　materials,　the　as-made　F-MoS2/NG　composite　shows　a　boosted　electrochemical　performance　for　reversible　lithium　storage.　It　delivers　a　high　reversible　capacity　of　1060　mAh/g　at　100　mA/g　even　after　150　cycles,　which　is　much　higher　than　416　mAh/g　of　the　control　MoS2/G　electrode.　The　kinetics　analysis　reveals　that　the　remarkable　rate　capability　of　FMoS2/NG　is　mainly　ascribed　to　a　pseudocapacitive　process,　which　is　rendered　by　its　unique　architecture　including　welldefined　MoS2　nanoflowers,　the　doping　of　nitrogen　onto　graphene,　and　the　enhanced　synergistic　effect　between　them.