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author:

Liu, Ning (Liu, Ning.) [1] | Wu, Ming-Hong (Wu, Ming-Hong.) [2] (Scholars:吴明红) | Xu, Gang (Xu, Gang.) [3] | Yuan, Qing (Yuan, Qing.) [4] | Tang, Liang (Tang, Liang.) [5] | Zhou, Jia-xin (Zhou, Jia-xin.) [6]

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CPCI-S

Abstract:

In this paper, the transient absorbance spectra and kinetics characteristics of DBP are studied in 266nm laser flash photolysis with three different mixed solvents. The transient species, assigned to DBP excited triplet, with maximum absorption at 300nm were observed in deoxidation system meanwhile its decay process accelerated obviously in O-2-statured system. By changing the concentration of DBP a series of observed decay rate constants were obtained and the self-quenching rate constants of DBP excited triplet were determined to be 4.5x10(7), 3.0x10(7) and 2.2x10(7) mol(-1) s(-1) L for ethanol/water, methanol/water and acetonitrile/water systems and self-decay rate constants to be 0.96x10(5) s(-1), 1.25x10(5) s(-1) and 1.33x10(5) s(-1), respectively. It revealed that the properties of DBP excited triplet have some relationship with the dielectric constants of solvents.

Keyword:

Dibutyl phthalate (DBP) dielectric constant excited triplet states kinetic laser flash photolysis

Community:

  • [ 1 ] [Liu, Ning]Shanghai Univ, Inst Appl Radiat, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 2 ] [Wu, Ming-Hong]Shanghai Univ, Inst Appl Radiat, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 3 ] [Xu, Gang]Shanghai Univ, Inst Appl Radiat, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 4 ] [Yuan, Qing]Shanghai Univ, Inst Appl Radiat, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 5 ] [Tang, Liang]Shanghai Univ, Inst Appl Radiat, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 6 ] [Zhou, Jia-xin]Shanghai Univ, Inst Appl Radiat, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China

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Source :

2009 INTERNATIONAL CONFERENCE ON ENERGY AND ENVIRONMENT TECHNOLOGY, VOL 3, PROCEEDINGS

Year: 2009

Page: 455-458

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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