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author:

Li, Wen (Li, Wen.) [1] | Yuan, Yao-feng (Yuan, Yao-feng.) [2] (Scholars:袁耀锋) | Li, Xiao-lin (Li, Xiao-lin.) [3] | Su, Xiao-long (Su, Xiao-long.) [4] | Sun, Wen-hua (Sun, Wen-hua.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

In order to investigate a noise-like signal appearing in dynamic mode measurement during laser flash photolysis experiments, five compounds were chosen which show this abnormal phenomenon. The reproducibility of this phenomenon was done repeatedly, indicating that it originates from each molecular structural property. Also their two regulation pattern or features were found by our analysis. One is a U-shaped curve of main frequency intensity with time and it seems to be directly related to the concentration of the T-1 excited state. The other is a high damping oscillation curve of the frequency shift with time and this curve seems to be indicating an energy transportation process from light into chemical energy. Finally, a possible origin of hydrogen nuclear optical resonance was proposed for the abnormal signal. (C) 2013 Elsevier B.V. All rights reserved.

Keyword:

Electronic triplet state Laser flash photolysis Nuclear spin Transient absorption signal

Community:

  • [ 1 ] [Li, Wen]Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
  • [ 2 ] [Yuan, Yao-feng]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
  • [ 3 ] [Su, Xiao-long]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
  • [ 4 ] [Li, Xiao-lin]Rhein Westfal TH Aachen, Inst Ferrous Met, D-52062 Aachen, Germany
  • [ 5 ] [Sun, Wen-hua]Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China

Reprint 's Address:

  • [Li, Wen]Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China

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Source :

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

ISSN: 1386-1425

Year: 2013

Volume: 105

Page: 569-576

2 . 1 2 9

JCR@2013

4 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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