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author:

Liu, Cheng (Liu, Cheng.) [1] | Liu, Hurunqing (Liu, Hurunqing.) [2] | Yu, Jimmy C. (Yu, Jimmy C..) [3] | Wu, Ling (Wu, Ling.) [4] (Scholars:吴棱) | Li, Zhaohui (Li, Zhaohui.) [5] (Scholars:李朝晖)

Indexed by:

Scopus SCIE CSCD

Abstract:

Photocatalysis, a promising technology to convert solar energy to chemical energy, is expected to relieve the global energy shortage and environmental pollution and therefore has attracted widespread recent research attention. Metal-organic frameworks (MOFs), a class of micro-mesoporous hybrid material constructed from metal or metal nodes interconnected with multi-dentated organic linkers, have recently been demonstrated to be promising photocatalysts for a variety of reactions relevant to environmental and energy concerns due to their unique structure and characteristics. Considering that MOF-based photocatalysis burgeoned rapidly during the past several years, and with an aim to develop more efficient MOF-based photocatalytic materials, it is still necessary to summarize the strategies already reported to improve the performance of MOF-based photocatalytic materials, even though several excellent reviews on MOF-based photocatalysis have already been published. In this review, four structural engineering strategies to improve the efficiency of MOF-based photocatalysis have been summarized. These strategies include metal doping, ligand functionalization, the fabrication of ultrathin 2D MOFs, and defect engineering. These methods aim to enhance light absorption, improve charge separation and transportation, and create more catalytic active sites. Personal opinions on the opportunities, challenges, and developing trends of MOF-based photocatalysis were addressed. This review aims to provide guidance for the rational development of advanced MOF-based photocatalysts by elucidating the inherent relationship between their structural properties and catalytic activity. Published by Elsevier B.V. All rights reserved.

Keyword:

Defect engineering Ligand functionalization Metal doping Metal-organic framework Photocatalysis Ultrathin 2D MOFs

Community:

  • [ 1 ] [Liu, Cheng]Fuzhou Univ, Res Inst Photocatalysis, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Liu, Hurunqing]Fuzhou Univ, Res Inst Photocatalysis, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Yu, Jimmy C.]Fuzhou Univ, Res Inst Photocatalysis, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Wu, Ling]Fuzhou Univ, Res Inst Photocatalysis, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Li, Zhaohui]Fuzhou Univ, Res Inst Photocatalysis, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 6 ] [Yu, Jimmy C.]Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2023

Volume: 55

Page: 1-19

1 5 . 7

JCR@2023

1 5 . 7 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 35

SCOPUS Cited Count: 16

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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