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A set of colour tuning K2Ba(MoO4)(2): Dy3+/Eu3+ (KBM: Dy3+/Eu3+) phosphors were fabricated by solid-state method. The phase purity of as-prepared materials was validated by XRD and DRS analyses. The KBM: 0.03Dy(3+) sample exhibits two major luminescence lines at 481 and 572 nm when excited by 351 nm light, corresponding to Dy3+ ions' typical transitions of F-4(9/2) -> H-6(J) (J = 15/2, 13/2). By introducing Eu3+ ions into KBM: 0.03Dy(3+) phosphor, the ET from Dy3+ to Eu3+ ions arises, leading to colour tuning from green via yellowish green to pink with changing Eu3+ ions' concentration, along with the lowest CCT of KBM: 0.03Dy(3+)/0.03Eu(3+) sample. It can be verified by PLE and PL spectra analysis combined with the decay times of KBM: 0.03Dy(3+)/yEu(3+) samples. The energy transfer mechanism is also expounded. Meanwhile, the emission intensities at 423 K still maintain 72.8% for Dy3+ ions and 91.2% for Eu3+ ions relative to 303 K of the KBM: 0.03Dy(3+)/0.03Eu(3+) sample, displaying its brilliant thermal stability. All these results connote that KBM: Dy3+/Eu3+ phosphors are prospected to be used for the near-UV excited white light-emitting diodes.
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BULLETIN OF MATERIALS SCIENCE
ISSN: 0250-4707
Year: 2024
Issue: 2
Volume: 47
1 . 9 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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