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author:

Ru, Jingjing (Ru, Jingjing.) [1] | Zhao, Bing (Zhao, Bing.) [2] | Zeng, Fan (Zeng, Fan.) [3] | Guo, Feiyun (Guo, Feiyun.) [4] (Scholars:郭飞云)

Indexed by:

EI Scopus SCIE

Abstract:

A set of colour tuning K2Ba(MoO4)(2): Dy3+/Eu3+ (KBM: Dy3+/Eu3+) phosphors were fabricated by solid-state method. The phase purity of as-prepared materials was validated by XRD and DRS analyses. The KBM: 0.03Dy(3+) sample exhibits two major luminescence lines at 481 and 572 nm when excited by 351 nm light, corresponding to Dy3+ ions' typical transitions of F-4(9/2) -> H-6(J) (J = 15/2, 13/2). By introducing Eu3+ ions into KBM: 0.03Dy(3+) phosphor, the ET from Dy3+ to Eu3+ ions arises, leading to colour tuning from green via yellowish green to pink with changing Eu3+ ions' concentration, along with the lowest CCT of KBM: 0.03Dy(3+)/0.03Eu(3+) sample. It can be verified by PLE and PL spectra analysis combined with the decay times of KBM: 0.03Dy(3+)/yEu(3+) samples. The energy transfer mechanism is also expounded. Meanwhile, the emission intensities at 423 K still maintain 72.8% for Dy3+ ions and 91.2% for Eu3+ ions relative to 303 K of the KBM: 0.03Dy(3+)/0.03Eu(3+) sample, displaying its brilliant thermal stability. All these results connote that KBM: Dy3+/Eu3+ phosphors are prospected to be used for the near-UV excited white light-emitting diodes.

Keyword:

energy transfer Phosphor thermal stable

Community:

  • [ 1 ] [Ru, Jingjing]Ningde Normal Univ, Fujian Prov Univ, Coll Chem & Mat, Key Lab Green Energy & Environm Catalysis, Ningde 352100, Peoples R China
  • [ 2 ] [Zeng, Fan]Ningde Normal Univ, Fujian Prov Univ, Coll Chem & Mat, Key Lab Green Energy & Environm Catalysis, Ningde 352100, Peoples R China
  • [ 3 ] [Zhao, Bing]Ningde Normal Univ, Coll Informat & Mech & Elect Engn, Ningde 352100, Peoples R China
  • [ 4 ] [Zeng, Fan]Fujian Normal Univ, Coll Environm Sci & Engn, Fuzhou 350007, Peoples R China
  • [ 5 ] [Guo, Feiyun]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Ru, Jingjing]Ningde Normal Univ, Fujian Prov Univ, Coll Chem & Mat, Key Lab Green Energy & Environm Catalysis, Ningde 352100, Peoples R China

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Source :

BULLETIN OF MATERIALS SCIENCE

ISSN: 0250-4707

Year: 2024

Issue: 2

Volume: 47

1 . 9 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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