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author:

Ke, Bingyuan (Ke, Bingyuan.) [1] | Zhang, Congcong (Zhang, Congcong.) [2] | Cheng, Shoulin (Cheng, Shoulin.) [3] | Li, Wangyang (Li, Wangyang.) [4] | Deng, Renming (Deng, Renming.) [5] | Zhang, Hong (Zhang, Hong.) [6] (Scholars:张红) | Lin, Jie (Lin, Jie.) [7] | Xie, Qingshui (Xie, Qingshui.) [8] | Qu, Baihua (Qu, Baihua.) [9] | Peng, Dong-Liang (Peng, Dong-Liang.) [10] | Wang, Xinghui (Wang, Xinghui.) [11] (Scholars:王星辉)

Indexed by:

ESCI EI

Abstract:

Along with the constantly evolving functional microsystems toward more diversification, the more rigorous design deliberation of pursuing higher mass-loading of electrode materials and low-temperature fabrication compatibility have imposed unprecedented demand on integrable all-solid-state thin-film microbatteries. While the classic thin-film intercalation cathode prepared by vacuum-based techniques inevitably encountered a post-annealing process, tape-casting technologies hold great merits both in terms of high-mass loading and low-temperature processing. In this work, a novel microbattery configuration is developed by the combination of traditional tape-casting thick electrodes and sputtered inorganic thin-film solid electrolytes (similar to 3 mu m lithium phosphorus oxynitride). Enabled by physically pressed or vapor-deposited Li as an anode, solid-state batteries with tape-casted LiFePO4 electrodes exhibit outstanding cyclability and stability. To meet integration requirements, LiFePO4/LiPON/Si microbatteries were successfully fabricated at low temperatures and found to achieve a wide operating temperature range. This novel configuration has good prospects in promoting the thin-film microbattery enabling a paradigm shift and satisfying diversified requirements.

Keyword:

all-solid-state batteries lithium phosphorus oxynitride on-chip integration silicon anodes tape-casting electrodes

Community:

  • [ 1 ] [Ke, Bingyuan]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhang, Congcong]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Cheng, Shoulin]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Li, Wangyang]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Deng, Renming]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Zhang, Hong]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Wang, Xinghui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Zhang, Hong]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou, Fujian, Peoples R China
  • [ 9 ] [Wang, Xinghui]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou, Fujian, Peoples R China
  • [ 10 ] [Zhang, Hong]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou, Peoples R China
  • [ 11 ] [Wang, Xinghui]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou, Peoples R China
  • [ 12 ] [Lin, Jie]Xiamen Univ, Coll Mat, Xiamen 361005, Peoples R China
  • [ 13 ] [Xie, Qingshui]Xiamen Univ, Coll Mat, Xiamen 361005, Peoples R China
  • [ 14 ] [Peng, Dong-Liang]Xiamen Univ, Coll Mat, Xiamen 361005, Peoples R China
  • [ 15 ] [Qu, Baihua]Chongqing Univ, Coll Mat Sci & Engn, Chongqing, Peoples R China

Reprint 's Address:

  • 王星辉

    [Wang, Xinghui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China;;[Peng, Dong-Liang]Xiamen Univ, Coll Mat, Xiamen 361005, Peoples R China

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Source :

INTERDISCIPLINARY MATERIALS

ISSN: 2767-4401

Year: 2024

Issue: 4

Volume: 3

Page: 621-631

2 4 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

Online/Total:211/10000268
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