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Abstract：
The enantioselective introduction of gem-difluorinated carbonyl (i. e. α,α-difluoro carbonyl) moieties into organic structures is a synthetically valuable but highly challenging approach. During the past decades, continuous efforts have been made for the developments of synthetic strategies for constructing C(sp3)−CF2COR chiral centers with high levels of enantioselectivities. This review summarizes and discusses the recent advance in the enantioselective construction of gem-difluorinated carbonyl moieties, which are organized according to the reaction categories. © 2024 Wiley-VCH GmbH.
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Advanced Synthesis and Catalysis
ISSN： 1615-4150
Year： 2024
Issue： 16
Volume： 366
Page： 3405-3416
4 . 4 0 0
JCR@2023
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ESI Highly Cited Papers on the List： 0 Unfold All
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30 Days PV： 1
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