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Lithium/fluorinated carbon (Li/CFx) batteries are greatly limited in their applications mostly due to poor rate performances. In this study, N,P co-doped biomass carbon was synthesized using melamine and phytic acid as doping sources, and the resulting product was then utilized as a precursor for CFx. The resulting fluorinated biomass carbon has a high degree of fluorination, exceeding the specific capacity of commercial fluorinated graphite while also demonstrating exceptional performance at high discharge rates. During the fluorination process, N,P-containing functional groups were removed from the crystalline lattice in the basal plane. This facilitates the formation of a defect-rich carbon matrix, enhancing the F/C ratio by improving the fluorinated active sites and obtaining more highly active semi-ionic bonds. Additionally, the abundant defects and porous structure promote Li+ diffusion. Density functional theory calculations indicated that doping modification effectively reduces the energy barrier for Li+ migration, enhancing Li+ transport efficiency. The prepared CFx delivers material with a maximum specific capacity of 919 mAhg(-1), while maintaining a specific capacity of 702 mAhg(-1) at a high discharge current density of 20C (with a capacity retention rate of 76.4%). In this study, fluorinated N,P co-doped biomass carbon, exhibiting ultrahigh capacity and high-rate performance, was prepared for the first time, which can potentially advance the commercialization of CFx.
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RARE METALS
ISSN: 1001-0521
Year: 2024
Issue: 1
Volume: 44
Page: 110-120
9 . 6 0 0
JCR@2023
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count: 4
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
Affiliated Colleges: