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author:

Yan, Ke (Yan, Ke.) [1] | Zou, Yan (Zou, Yan.) [2] | Bao, Liang-Xue (Bao, Liang-Xue.) [3] | Xia, Qi (Xia, Qi.) [4] | Meng, Ling-Yi (Meng, Ling-Yi.) [5] | Lin, Hai-Chen (Lin, Hai-Chen.) [6] | Chen, Hui-Xin (Chen, Hui-Xin.) [7] | Yue, Hong-Jun (Yue, Hong-Jun.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

Lithium/fluorinated carbon (Li/CFx) batteries are greatly limited in their applications mostly due to poor rate performances. In this study, N,P co-doped biomass carbon was synthesized using melamine and phytic acid as doping sources, and the resulting product was then utilized as a precursor for CFx. The resulting fluorinated biomass carbon has a high degree of fluorination, exceeding the specific capacity of commercial fluorinated graphite while also demonstrating exceptional performance at high discharge rates. During the fluorination process, N,P-containing functional groups were removed from the crystalline lattice in the basal plane. This facilitates the formation of a defect-rich carbon matrix, enhancing the F/C ratio by improving the fluorinated active sites and obtaining more highly active semi-ionic bonds. Additionally, the abundant defects and porous structure promote Li+ diffusion. Density functional theory calculations indicated that doping modification effectively reduces the energy barrier for Li+ migration, enhancing Li+ transport efficiency. The prepared CFx delivers material with a maximum specific capacity of 919 mAhg(-1), while maintaining a specific capacity of 702 mAhg(-1) at a high discharge current density of 20C (with a capacity retention rate of 76.4%). In this study, fluorinated N,P co-doped biomass carbon, exhibiting ultrahigh capacity and high-rate performance, was prepared for the first time, which can potentially advance the commercialization of CFx.

Keyword:

Biomass carbon Heteroatom doping High performance Li/CFx primary batteries

Community:

  • [ 1 ] [Yan, Ke]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zou, Yan]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 3 ] [Yue, Hong-Jun]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 4 ] [Yan, Ke]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 5 ] [Zou, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 6 ] [Bao, Liang-Xue]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 7 ] [Xia, Qi]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 8 ] [Meng, Ling-Yi]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 9 ] [Chen, Hui-Xin]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 10 ] [Yue, Hong-Jun]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 11 ] [Yan, Ke]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 12 ] [Zou, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 13 ] [Bao, Liang-Xue]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 14 ] [Xia, Qi]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 15 ] [Meng, Ling-Yi]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 16 ] [Chen, Hui-Xin]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 17 ] [Yue, Hong-Jun]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 18 ] [Yan, Ke]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 19 ] [Zou, Yan]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 20 ] [Bao, Liang-Xue]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 21 ] [Xia, Qi]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 22 ] [Meng, Ling-Yi]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 23 ] [Chen, Hui-Xin]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 24 ] [Yue, Hong-Jun]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 25 ] [Lin, Hai-Chen]Univ Calif San Diego, Sustainable Power & Energy Ctr, Nano Engn Dept, La Jolla, CA 92093 USA

Reprint 's Address:

  • [Yue, Hong-Jun]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China;;[Chen, Hui-Xin]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China;;[Yue, Hong-Jun]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China;;[Chen, Hui-Xin]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China;;[Yue, Hong-Jun]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China;;

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Source :

RARE METALS

ISSN: 1001-0521

Year: 2024

Issue: 1

Volume: 44

Page: 110-120

9 . 6 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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