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author:

Ye, Xiaoxia (Ye, Xiaoxia.) [1] (Scholars:叶晓霞) | Chen, Xueying (Chen, Xueying.) [2] | Chen, Dongjun (Chen, Dongjun.) [3] | Qian, Zhen (Qian, Zhen.) [4] | Duan, Yuxin (Duan, Yuxin.) [5] | Du, Xiaowei (Du, Xiaowei.) [6] | Lin, Chunxiang (Lin, Chunxiang.) [7] (Scholars:林春香) | Chen, Jie (Chen, Jie.) [8] (Scholars:陈杰) | Luo, Wei (Luo, Wei.) [9]

Indexed by:

EI Scopus SCIE

Abstract:

The sustainability of uranium-based nuclear energy relies on the development of quick and effective uranium adsorbents. Herein, we propose a facile post-synthetic technique by grafting amino-functional groups onto the fluorenone-functionalized conjugated microporous poly(aniline)s (CMPs) network to acquire a novel class of N decorated polymers for uranium capture. By leveraging the abundant N sites and microenvironment-containing molecular structure, CMPA-F-BDA showcases excellent UO22+ adsorption performance with fast adsorption kinetic with initial adsorption rate up to 43.78 mg g(-1) min(-1), Langmuir adsorption capacity of 443 mg g(-1) and exceptional adsorption selectivity of Kd = 1.3 x 10(7) mL g(-1) even in the serious presence of competitive cations. Additionally, CMPA-F-BDA could treat up to 18.5 L g(-1) of low-concentration uranium solution (1 mg L-1) and actual seawater, removing 87.9% of uranium from 10 L of seawater, and has excellent reusability. This study demonstrates the bright future of CMPs for the extraction of low-concentration uranium.

Keyword:

Amino-functional groups Conjugated microporous polymers Microenvironment design Post-functionalization Seawater Uranium extraction

Community:

  • [ 1 ] [Ye, Xiaoxia]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Chen, Xueying]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Duan, Yuxin]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Du, Xiaowei]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Lin, Chunxiang]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Chen, Dongjun]Fujian Radiat Environm Supervis Stn, Fuzhou 350013, Peoples R China
  • [ 7 ] [Qian, Zhen]Fujian Radiat Environm Supervis Stn, Fuzhou 350013, Peoples R China
  • [ 8 ] [Chen, Jie]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 9 ] [Luo, Wei]Sichuan Univ, Coll Biomass Sci & Engn, Chengdu 610065, Peoples R China

Reprint 's Address:

  • [Chen, Jie]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China;;[Luo, Wei]Sichuan Univ, Coll Biomass Sci & Engn, Chengdu 610065, Peoples R China;;

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2024

Volume: 353

8 . 2 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

Online/Total:201/10000282
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