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The sustainability of uranium-based nuclear energy relies on the development of quick and effective uranium adsorbents. Herein, we propose a facile post-synthetic technique by grafting amino-functional groups onto the fluorenone-functionalized conjugated microporous poly(aniline)s (CMPs) network to acquire a novel class of N decorated polymers for uranium capture. By leveraging the abundant N sites and microenvironment-containing molecular structure, CMPA-F-BDA showcases excellent UO22+ adsorption performance with fast adsorption kinetic with initial adsorption rate up to 43.78 mg g(-1) min(-1), Langmuir adsorption capacity of 443 mg g(-1) and exceptional adsorption selectivity of Kd = 1.3 x 10(7) mL g(-1) even in the serious presence of competitive cations. Additionally, CMPA-F-BDA could treat up to 18.5 L g(-1) of low-concentration uranium solution (1 mg L-1) and actual seawater, removing 87.9% of uranium from 10 L of seawater, and has excellent reusability. This study demonstrates the bright future of CMPs for the extraction of low-concentration uranium.
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SEPARATION AND PURIFICATION TECHNOLOGY
ISSN: 1383-5866
Year: 2024
Volume: 353
8 . 2 0 0
JCR@2023
Cited Count:
WoS CC Cited Count: 5
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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