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author:

Lin, Lichao (Lin, Lichao.) [1] | Wu, Lusha (Wu, Lusha.) [2] | Wang, Yating (Wang, Yating.) [3] | Jiang, Zhou (Jiang, Zhou.) [4] (Scholars:江舟) | Wang, Jian (Wang, Jian.) [5] (Scholars:王建)

Indexed by:

EI Scopus SCIE

Abstract:

The accurate monitoring of sulfide ion concentrations is vital for ensuring food safety, but current detection methods are often cumbersome and confined to laboratories. This study introduces an innovative paper-based colorimetric sensor that leverages the peroxidase-like activity of cobalt tetrasulfonate phthalocyanine (CoTsPc) for rapid, sensitive, and selective sulfide ion quantification. The underlying mechanism relies on the interaction between cobalt and sulfide ions, modulating the catalytic efficiency of CoTsPc and triggering a visible color change when 3,3 ',5,5 '-tetramethylbenzidine (TMB) and hydrogen peroxide are present. By controlling solvent evaporation, the reaction kinetics are standardized, enabling reproducible and accurate colorimetric measurements. Experimental results show that adding sulfide ions to the TMB-H2O2 reaction system causes a gradual decrease in color intensity on the paper substrate. This change verifies effectiveness of the sensor, highlighting its potential for reliable sulfide ion detection in food safety applications, while providing a simple and portable alternative to conventional methods.

Keyword:

3 ' 5 ' -tetramethylbenzidine (TMB) Cobalt tetrasulfonate phthalocyanine (CoTsPc) Colorimetric measurements Hydrogen peroxide Peroxidase-mimicking activity

Community:

  • [ 1 ] [Wu, Lusha]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Anal & Detect Food Safety, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Wang, Yating]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Anal & Detect Food Safety, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Wang, Jian]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Anal & Detect Food Safety, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Jiang, Zhou]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Canc Metastasis Chemoprevent &, Fuzhou 350108, Peoples R China
  • [ 5 ] [Lin, Lichao]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 江舟 王建

    [Jiang, Zhou]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China;;[Wang, Jian]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China

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Source :

FOOD CHEMISTRY

ISSN: 0308-8146

Year: 2024

Volume: 465

8 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

Online/Total:223/10000468
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