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author:

Wang, Dong (Wang, Dong.) [1] | Wu, Shihao (Wu, Shihao.) [2] | Lu, Kai (Lu, Kai.) [3] (Scholars:卢凯) | Zhang, Yapei (Zhang, Yapei.) [4] | Su, G. H. (Su, G. H..) [5] | Liu, Xi (Liu, Xi.) [6] (Scholars:刘曦)

Indexed by:

EI Scopus SCIE

Abstract:

In our previous studies of Cr-coated Zr alloy cladding, models for the oxidation and degradation of Cr coating and for the oxidation and phase transformation of Zr alloy have been established. On these foundations, oxygen flux models for Cr-Zr non-eutectic and eutectic conditions are developed in this paper, enabling a comprehensive simulation of the oxidation processes of Cr-coated Zr alloy. The models are validated through oxidation experiments under isothermal and temperature ramp conditions, showing good agreement with the experimental data. The models can effectively simulate the processes where, under non-eutectic conditions, oxygen atoms first dissolve into the prior beta-Zr matrix after coating degradation, followed by the formation of alpha-Zr(O) and eventually ZrO2. For conditions with eutectic reaction, model assumption of immediate complete coating failure could lead to overestimation of substrate oxidation extent at low heating rates. This prediction deviation decreases as heating rate increases.

Keyword:

Cr-coated Zr alloy Diffusion High-temperature oxidation Model development Oxygen flux

Community:

  • [ 1 ] [Wang, Dong]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Lu, Kai]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Liu, Xi]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Wang, Dong]Fuzhou Univ, Inst Nucl Energy Technol, Fuzhou 350108, Peoples R China
  • [ 5 ] [Lu, Kai]Fuzhou Univ, Inst Nucl Energy Technol, Fuzhou 350108, Peoples R China
  • [ 6 ] [Liu, Xi]Fuzhou Univ, Inst Nucl Energy Technol, Fuzhou 350108, Peoples R China
  • [ 7 ] [Wu, Shihao]Xi An Jiao Tong Univ, Shaanxi Engn Res Ctr Adv Nucl Energy, Sch Nucl Sci & Technol, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China
  • [ 8 ] [Zhang, Yapei]Xi An Jiao Tong Univ, Shaanxi Engn Res Ctr Adv Nucl Energy, Sch Nucl Sci & Technol, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China
  • [ 9 ] [Su, G. H.]Xi An Jiao Tong Univ, Shaanxi Engn Res Ctr Adv Nucl Energy, Sch Nucl Sci & Technol, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China

Reprint 's Address:

  • [Lu, Kai]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China;;[Zhang, Yapei]Xi An Jiao Tong Univ, Shaanxi Engn Res Ctr Adv Nucl Energy, Sch Nucl Sci & Technol, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China;;

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Source :

JOURNAL OF NUCLEAR MATERIALS

ISSN: 0022-3115

Year: 2025

Volume: 606

2 . 8 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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