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author:

Wang, D. (Wang, D..) [1] | Wu, S. (Wu, S..) [2] | Lu, K. (Lu, K..) [3] | Zhang, Y. (Zhang, Y..) [4] | Su, G.H. (Su, G.H..) [5] | Liu, X. (Liu, X..) [6]

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Scopus

Abstract:

In our previous studies of Cr-coated Zr alloy cladding, models for the oxidation and degradation of Cr coating and for the oxidation and phase transformation of Zr alloy have been established. On these foundations, oxygen flux models for Cr-Zr non-eutectic and eutectic conditions are developed in this paper, enabling a comprehensive simulation of the oxidation processes of Cr-coated Zr alloy. The models are validated through oxidation experiments under isothermal and temperature ramp conditions, showing good agreement with the experimental data. The models can effectively simulate the processes where, under non-eutectic conditions, oxygen atoms first dissolve into the prior β-Zr matrix after coating degradation, followed by the formation of α-Zr(O) and eventually ZrO2. For conditions with eutectic reaction, model assumption of immediate complete coating failure could lead to overestimation of substrate oxidation extent at low heating rates. This prediction deviation decreases as heating rate increases. © 2025 Elsevier B.V.

Keyword:

Cr-coated Zr alloy Diffusion High-temperature oxidation Model development Oxygen flux

Community:

  • [ 1 ] [Wang D.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Wang D.]Institute of Nuclear Energy Technology, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Wu S.]School of Nuclear Science and Technology, Shaanxi Engineering Research Center of Advanced Nuclear Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an, 710049, China
  • [ 4 ] [Lu K.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Lu K.]Institute of Nuclear Energy Technology, Fuzhou University, Fuzhou, 350108, China
  • [ 6 ] [Zhang Y.]School of Nuclear Science and Technology, Shaanxi Engineering Research Center of Advanced Nuclear Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an, 710049, China
  • [ 7 ] [Su G.H.]School of Nuclear Science and Technology, Shaanxi Engineering Research Center of Advanced Nuclear Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an, 710049, China
  • [ 8 ] [Liu X.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 9 ] [Liu X.]Institute of Nuclear Energy Technology, Fuzhou University, Fuzhou, 350108, China

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Source :

Journal of Nuclear Materials

ISSN: 0022-3115

Year: 2025

Volume: 606

2 . 8 0 0

JCR@2023

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ESI Highly Cited Papers on the List: 0 Unfold All

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Chinese Cited Count:

30 Days PV: 0

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