Electrochemical Conversion of N-Sulfinylamines to Sulfonimidoyl Fluorides - Details

author：

Gao, F.-L. (Gao, F.-L..) ^[1] | He, X. (He, X..) ^[2] | Zhao, B. (Zhao, B..) ^[3] | Lin, Y. (Lin, Y..) ^[4] | Ye, K.-Y. (Ye, K.-Y..) ^[5]

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Abstract：

The　invention　of　novel　linkers　is　a　long-lasting　task　in　the　area　of　the　sulfur(VI)　fluoride　exchange　reaction　(SuFEx).　Compared　with　the　most　frequently　investigated　sulfonyl　fluorides,　synthetic　accessibility　toward　its　mono-aza　isostere,　i.e.,　sulfonimidoyl　fluorides　is　still　limited.　Herein,　we　report　an　electrochemical　carbonfluorination　of　the　readily　available　N-sulfinylamines　to　access　various　aryl　and　alkyl　sulfonimidoyl　fluorides.　The　transformation　is　characterized　by　the　ready　availability　of　starting　materials,　mild　reaction　conditions,　and　obviating　metal　catalysts　and　chemical　oxidants.　©　2024　SIOC,　CAS,　Shanghai,　&　WILEY-VCH　GmbH.

Keyword：

Electrochemical Green chemistry N-Sulfinylamines Sulfonimidoyl fluorides Sulfur(VI) fluoride exchange reaction

Community：

[ 1 ] [Gao F.-L.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 2 ] [He X.]School of Chemistry and Chemical Engineering, Henan Normal University, Henan, Xinxiang, 453007, China
[ 3 ] [Zhao B.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 4 ] [Lin Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 5 ] [Ye K.-Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 6 ] [Ye K.-Y.]School of Chemistry and Chemical Engineering, Henan Normal University, Henan, Xinxiang, 453007, China

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Source ：

Chinese Journal of Chemistry

ISSN： 1001-604X

Year： 2024

Issue： 7

Volume： 43

Page： 769-774

5 . 5 0 0

JCR@2023

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