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author:

Gao, Fang-Ling (Gao, Fang-Ling.) [1] | He, Xinglei (He, Xinglei.) [2] | Zhao, Bin (Zhao, Bin.) [3] | Lin, Yuqi (Lin, Yuqi.) [4] (Scholars:林雨琦) | Ye, Ke-Yin (Ye, Ke-Yin.) [5] (Scholars:叶克印)

Indexed by:

Scopus SCIE

Abstract:

The invention of novel linkers is a long-lasting task in the area of the sulfur(VI) fluoride exchange reaction (SuFEx). Compared with the most frequently investigated sulfonyl fluorides, synthetic accessibility toward its mono-aza isostere, i.e., sulfonimidoyl fluorides is still limited. Herein, we report an electrochemical carbonfluorination of the readily available N-sulfinylamines to access various aryl and alkyl sulfonimidoyl fluorides. The transformation is characterized by the ready availability of starting materials, mild reaction conditions, and obviating metal catalysts and chemical oxidants.

Keyword:

Electrochemical Green chemistry N-Sulfinylamines Sulfonimidoyl fluorides Sulfur(VI) fluoride exchange reaction

Community:

  • [ 1 ] [Gao, Fang-Ling]Fujian Prov Univ, Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zhao, Bin]Fujian Prov Univ, Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Lin, Yuqi]Fujian Prov Univ, Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Ye, Ke-Yin]Fujian Prov Univ, Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [He, Xinglei]Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
  • [ 6 ] [Ye, Ke-Yin]Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China

Reprint 's Address:

  • 林雨琦 叶克印

    [Lin, Yuqi]Fujian Prov Univ, Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China;;[Ye, Ke-Yin]Fujian Prov Univ, Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China;;[Ye, Ke-Yin]Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China

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Source :

CHINESE JOURNAL OF CHEMISTRY

ISSN: 1001-604X

Year: 2024

Issue: 7

Volume: 43

Page: 769-774

5 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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