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author:

Huang, Q. (Huang, Q..) [1] | Yao, P. (Yao, P..) [2] | Li, W. (Li, W..) [3] | Chen, L. (Chen, L..) [4] | Jian, Y. (Jian, Y..) [5] | Chen, J. (Chen, J..) [6] | Zhang, H. (Zhang, H..) [7] | Wang, X. (Wang, X..) [8]

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Scopus

Abstract:

The rapid evolution of miniaturized portable and wearable electronics has significantly intensified the demand for miniature energy storage devices featuring high energy density, cost-effective fabrication, and scalable manufacturing. 3D printing of energy storage electrodes provides new possibilities for meeting these emerging needs. Herein, we present the development of 3D-printed planar asymmetric quasi-solid-state micro-supercapacitors (MSCs) with high areal energy density, utilizing cobalt hexacyanoferrate (CoHCF) as the positive electrode and activated carbon (AC) as the negative electrode. The as-prepared MSCs exhibit a broad operating potential window of 1.5 V and exceptional areal energy and power densities of 415.8 μWh cm−2 and 7.5 mW cm−2, respectively, along with an impressive cycling retention rate of 104.9 % even after 15,000 cycles. Furthermore, the printed MSCs display excellent deformation-tolerant ability and integrability. These results highlight the potential of CoHCF//AC asymmetric MSCs as promising candidates for miniature, flexible, and integrable energy storage applications. © 2025 Elsevier Ltd

Keyword:

3D printing Additive manufacturing Asymmetric supercapacitor Miniature power source Prussian blue

Community:

  • [ 1 ] [Huang Q.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Yao P.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Li W.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Li W.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350108, China
  • [ 5 ] [Li W.]Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou, 213000, China
  • [ 6 ] [Chen L.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Jian Y.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 8 ] [Chen J.]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, 350007, China
  • [ 9 ] [Zhang H.]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, 350007, China
  • [ 10 ] [Wang X.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 11 ] [Wang X.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350108, China
  • [ 12 ] [Wang X.]Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou, 213000, China

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Source :

Chemical Engineering Science

ISSN: 0009-2509

Year: 2025

Volume: 312

4 . 1 0 0

JCR@2023

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ESI Highly Cited Papers on the List: 0 Unfold All

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Chinese Cited Count:

30 Days PV: 1

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