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author:

Peng, Shuijiao (Peng, Shuijiao.) [1] | Jiang, Xingzong (Jiang, Xingzong.) [2] | Xiang, Xiaotong (Xiang, Xiaotong.) [3] | Chen, Kai (Chen, Kai.) [4] | Chen, Guoqi (Chen, Guoqi.) [5] | Jiang, Xiancai (Jiang, Xiancai.) [6] (Scholars:江献财) | Hou, Linxi (Hou, Linxi.) [7] (Scholars:侯琳熙)

Indexed by:

EI Scopus SCIE

Abstract:

In this work, the high-performance and flexible solid-state supercapacitors were fabricated based on poly(vinyl alcohol)(PVA)/NaCl/glycerol hydrogel electrolyte and activated carbon electrodes. A novel assembling method was proposed according to the formation properties of PVA/NaCl/glycerol hydrogel electrolyte. PVA/NaCl/glycerol hydrogel electrolyte could be quickly formed in a short time at room temperature. Thus the PVA/NaCl/glycerol solution was coated onto the activated carbon electrodes and the hydrogel electrolyte was in situ formed on the surface of the activated electrodes. Meanwhile, the PVA/NaCl/glycerol hydrogel electrolyte could retain outstanding flexibility and ionic conductivity at a low temperature, which makes the solid-state supercapacitor have excellent low-temperature tolerance. Thus, the electrochemical measurements of the assembled supercapacitor were performed at room temperature and a low temperature of -23 degrees C, respectively. The flexible supercapacitor can show an outstanding flexibility and electrochemical performance at -23 degrees C. Its specific capacitance can remain approximately 81.0% of its initial specific capacitance at room temperature and the capacitance retention could keep 90.5% of the initial capacitance retention at -23 degrees C. It also could be anticipated that this multifunctional flexible supercapacitor with the PVA/NaCl/glycerol hydrogel electrolyte would have broad applications in modern flexible energy storage device. (C) 2019 Elsevier Ltd. All rights reserved.

Keyword:

Hydrogel electrolyte Low-temperature tolerance Poly(vinyl alcohol) Solid-state Supercapacitor

Community:

  • [ 1 ] [Peng, Shuijiao]Fuzhou Univ, Sch Chem Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 2 ] [Jiang, Xingzong]Fuzhou Univ, Sch Chem Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 3 ] [Xiang, Xiaotong]Fuzhou Univ, Sch Chem Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 4 ] [Chen, Kai]Fuzhou Univ, Sch Chem Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 5 ] [Chen, Guoqi]Fuzhou Univ, Sch Chem Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 6 ] [Jiang, Xiancai]Fuzhou Univ, Sch Chem Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 7 ] [Hou, Linxi]Fuzhou Univ, Sch Chem Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 8 ] [Jiang, Xiancai]Sichuan Univ, State Key Lab Polymer Mat Engn, Chengdu 610065, Sichuan, Peoples R China

Reprint 's Address:

  • 江献财

    [Jiang, Xiancai]Fuzhou Univ, Sch Chem Engn, Fuzhou 350118, Fujian, Peoples R China

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Source :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

Year: 2019

Volume: 324

6 . 2 1 5

JCR@2019

5 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 74

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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