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author:

Chen, Guoqi (Chen, Guoqi.) [1] | Hu, Oudong (Hu, Oudong.) [2] | Lu, Jing (Lu, Jing.) [3] | Gu, Jianfeng (Gu, Jianfeng.) [4] | Chen, Kai (Chen, Kai.) [5] | Huang, Jianren (Huang, Jianren.) [6] | Hou, Linxi (Hou, Linxi.) [7] (Scholars:侯琳熙) | Jiang, Xiancai (Jiang, Xiancai.) [8] (Scholars:江献财)

Indexed by:

EI SCIE

Abstract:

Adhesion and stretchable hydrogel electrolytes have emerged as an ideal candidate in the fabrication of flexible all-solid-state supercapacitor. However, the conventional hydrogel electrolyte would inevitably deteriorate or even deactivate after mechanical damage (stretching and cutting) or dehydrating. As an alternative to overcome these limitations, we designed a dynamic elastic molecular double network (DN) hydrogel electrolyte consisting of poly(vinyl alcohol) (PVA) and poly(acrylic amide-co-2-acrylamido-2-methylpropane sulfonic acid) (P(AMAMPS)) networks. Glycerin was introduced into the PVA/P(AM-AMPS) system to enhance the inter-chain physically-crosslinked network. This DN hydrogel electrolyte exhibited remarkable stretchability (over 894%), strong adhesion (37.00 kPa to carbon materials) and high ionic conductivity (3.85 S m(-1)). In particular, the dynamic physically-crosslinked network endowed hydrogel electrolyte eminent mechanical tolerance. The toughness of hydrogel kept stable in 10 times 500% strain loading-unloading tensile test. Along with the CNT electrodes, a highly flexible all-solid-state supercapacitor was prepared by using our developed DN hydrogel as electrolyte. This hydrogel-based supercapacitor exhibited high capacitance (85.25 mF cm(-2) at a current density of 0.5 mA cm(-2)). More importantly, benefiting from the unique network structure of hydrogel electrolyte, a steady bonding interface between electrode and electrolyte was constructed. Electrochemical performance of supercapacitor could be maintained in different working conditions. The capacitance of a device was stable upon stretching (200% strain) or bending (angle of 0-180.). In addition, hydrogel based supercapacitor could be resumed after dehydrating or cutting by accident. Our results provide a new slight into multifunctional all-solid-state supercapacitor preparation. We hope this hydrogel will promote the development of wearable energy storage.

Keyword:

Dynamic network Flexible supercapacitor Hydrogel electrolyte Resumability Stretchability

Community:

  • [ 1 ] [Chen, Guoqi]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 2 ] [Hu, Oudong]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 3 ] [Lu, Jing]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 4 ] [Gu, Jianfeng]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 5 ] [Chen, Kai]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 6 ] [Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 7 ] [Jiang, Xiancai]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China
  • [ 8 ] [Huang, Jianren]Chinese Acad Sci, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Key Lab Nanomat, Fujian Inst Res Struct Matter, Yangqiao West Rd 155, Fuzhou 350002, Peoples R China
  • [ 9 ] [Huang, Jianren]Fuzhou Univ, Coll Mech Engn & Automat, Xueyuan Rd 2, Fuzhou 350108, Peoples R China
  • [ 10 ] [Jiang, Xiancai]Qingyuan Innovat Lab, Quanzhou 362114, Peoples R China
  • [ 11 ] [Jiang, Xiancai]Sichuan Univ, State Key Lab Polymer Mat Engn, Yihuang Rd South 1 24, Chengdu 610065, Peoples R China

Reprint 's Address:

  • 江献财

    [Jiang, Xiancai]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Peoples R China

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2021

Volume: 425

1 6 . 7 4 4

JCR@2021

1 3 . 4 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:105

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 84

SCOPUS Cited Count: 66

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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