Rhodium(III)/Amine Synergistically Catalyzed Enantioselective Alkylation of Aldehydes with alpha,beta-Unsaturated 2-Acyl Imidazoles - Details

author：

Gong, Jun (Gong, Jun.) ^[1] | Li, Kuan (Li, Kuan.) ^[2] | Qurban, Saira (Qurban, Saira.) ^[3] | Kang, Qiang (Kang, Qiang.) ^[4]

Indexed by：

Scopus SCIE CSCD

Abstract：

A　synergistic　catalysis　combination　of　chiral-at-metal　rhodium　complex　and　amine　catalyst　was　developed　for　enantioselective　alkylation　of　aldehydes　with　alpha,beta-unsaturated　2-acyl　imidazoles.　The　corresponding　adducts　were　obtained　in　good　yields　with　excellent　enantioselectivities　(up　to　99%　ee).

Keyword：

alkylation of aldehyde chiral-at-metal complex synergistic catalysis

Community：

[ 1 ] [Gong, Jun]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
[ 2 ] [Qurban, Saira]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
[ 3 ] [Kang, Qiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
[ 4 ] [Li, Kuan]Fuzhou Univ, Dept Chem, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address：

[Kang, Qiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China

Email：

kangq@fjirsm.ac.cn

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Version：

Rhodium(III)/Amine Synergistically Catalyzed Enantioselective Alkylation of Aldehydes with α,β-Unsaturated 2-Acyl Imidazoles
2016，Chinese Journal of Chemistry
Rhodium(Ⅲ)/Amine Synergistically Catalyzed Enantioselective Alkylation of Aldehydes with α,β-Unsaturated 2-Acyl Imidazoles
2016，中国化学（英文版）

Related Keywords：

Enantioselective Conjugate Addition of 2-Acylimidazoles with Nitroalkenes Promoted by Chiral-at-Metal Rhodium(III) Complexes
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Source ：

CHINESE JOURNAL OF CHEMISTRY

ISSN： 1001-604X

CN： 31-1547/O6

Year： 2016

Issue： 12

Volume： 34

Page： 1225-1235

1 . 8 5 2

JCR@2016

5 . 5 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

ESI HC Threshold：235

JCR Journal Grade：3

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 35

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

Affiliated Colleges：

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