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author:

Song, Kaixin (Song, Kaixin.) [1] | Zhang, Fangfang (Zhang, Fangfang.) [2] | Chen, Daqin (Chen, Daqin.) [3] | Wu, Song (Wu, Song.) [4] | Zheng, Peng (Zheng, Peng.) [5] | Huang, Qingming (Huang, Qingming.) [6] (Scholars:黄清明) | Jiang, Jun (Jiang, Jun.) [7] | Xu, Junming (Xu, Junming.) [8] | Qin, Huibin (Qin, Huibin.) [9]

Indexed by:

EI Scopus SCIE

Abstract:

Si3N4 modified Li2Sr0.995SiO4:0.005Eu(2+) (Li2Sr0.995SiO4-3x/2Nx:0.005Eu(2+)) phosphors were synthesized with the conventional solid-state reaction in the reduced atmosphere. The crystal structure and vibrational modes were analyzed by X-ray diffraction, Raman scattering spectroscopy and Rietveld crystal structure refinement. Photoluminescence (PL) and photoluminescence excitation (PLE) spectra showed that Li2Sr0.995SiO4-3x/2Nx:0.005Eu(2+) powder exhibited a broad yellow emission band centered at 560 nm under the excitation of 460 nm visible light, due to the 4f(6)5d(1) -> 4f(7) transition of Eu2+. The partial nitridation of Li2Sr0.995SiO4-3x/2Nx:0.005Eu(2+) (x=0.01) phosphors led to a large enhancement in the luminescence intensity, as much as 190%. At the same time, the fluorescence decay behavior curves further showed that the photoluminescence efficiencies of Li2Sr0.995SiO4-3x/2Nx:0.005Eu(2+) phosphors were enhanced by addition of Si3N4. The temperature quenching characteristics confirmed that the oxynitride based Li2Sr0.995SiO4-3x/2Nx:0.005Eu(2+) showed slightly higher stability. It is implied that Li2Sr0.995SiO4-3x/2Nx:0.005Eu(2+) phosphors had a possible potential application on white LEDs to match blue light chips. (C) 2015 Elsevier Ltd. All rights reserved.

Keyword:

Crystal structure Optical materials Optical properties X-ray diffraction

Community:

  • [ 1 ] [Song, Kaixin]Hangzhou Dianzi Univ, Coll Elect Informat & Engn, Hangzhou 310018, Zhejiang, Peoples R China
  • [ 2 ] [Zhang, Fangfang]Hangzhou Dianzi Univ, Coll Elect Informat & Engn, Hangzhou 310018, Zhejiang, Peoples R China
  • [ 3 ] [Wu, Song]Hangzhou Dianzi Univ, Coll Elect Informat & Engn, Hangzhou 310018, Zhejiang, Peoples R China
  • [ 4 ] [Zheng, Peng]Hangzhou Dianzi Univ, Coll Elect Informat & Engn, Hangzhou 310018, Zhejiang, Peoples R China
  • [ 5 ] [Xu, Junming]Hangzhou Dianzi Univ, Coll Elect Informat & Engn, Hangzhou 310018, Zhejiang, Peoples R China
  • [ 6 ] [Qin, Huibin]Hangzhou Dianzi Univ, Coll Elect Informat & Engn, Hangzhou 310018, Zhejiang, Peoples R China
  • [ 7 ] [Chen, Daqin]Hangzhou Dianzi Univ, Coll Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China
  • [ 8 ] [Huang, Qingming]Fuzhou Univ, Instrument Anal & Testing Ctr, Fuzhou 350002, Peoples R China
  • [ 9 ] [Jiang, Jun]Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China

Reprint 's Address:

  • [Song, Kaixin]Hangzhou Dianzi Univ, Coll Elect Informat & Engn, Hangzhou 310018, Zhejiang, Peoples R China

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Source :

MATERIALS RESEARCH BULLETIN

ISSN: 0025-5408

Year: 2015

Volume: 70

Page: 309-314

2 . 4 3 5

JCR@2015

5 . 3 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:335

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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