Synthesis of the first 1,3-disubstituted 1,3-butadienyl heteroannular bridged [4]ferrocenophane - Details

author：

Wu, Kai-Qiang (Wu, Kai-Qiang.) ^[1] | Xie, Li-Li (Xie, Li-Li.) ^[2] (Scholars：谢莉莉) | Zhang, Yong-Fan (Zhang, Yong-Fan.) ^[3] (Scholars：章永凡) | Xu, Feng-Bo (Xu, Feng-Bo.) ^[4] | Yuan, Yao-Feng (Yuan, Yao-Feng.) ^[5] (Scholars：袁耀锋)

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EI Scopus SCIE

Abstract：

An　unusual　heteroannular　cyclization　of　methyl　4-(((1＇-(trimethylsilyl)ethynyl)ferrocenyl)ethynyl)　benzoate　(11)　under　the　basic　desilylation　condition　yielded　1,1＇-(l-methoxy-3-(4＇-(methoxycarbonyl)phenyl)-1,3-butadienylene)　ferrocene　(7),　the　first　reported　1,3-disubstituted　1,3-butadienyl　heteroannular　bridged　[4]ferrocenophane.　Compound　7　has　been　characterized　by　elemental　analysis,　IR　spectra,　H-1　NMR　spectroscopy　and　X-ray　diffraction　analysis.　The　electrochemical　behavior　has　been　investigated　by　cyclic　voltammetry.　The　DFT　calculation　results　of　7　are　also　reported.　(C)　2011　Elsevier　B.　V.　All　rights　reserved.

Keyword：

[4]Ferrocenophane Alkynylferrocene Desilylation Heteroannular cyclization

Community：

[ 1 ] [Wu, Kai-Qiang]Fuzhou Univ, Dept Chem, Fuzhou 350108, Fujian, Peoples R China
[ 2 ] [Xie, Li-Li]Fuzhou Univ, Dept Chem, Fuzhou 350108, Fujian, Peoples R China
[ 3 ] [Zhang, Yong-Fan]Fuzhou Univ, Dept Chem, Fuzhou 350108, Fujian, Peoples R China
[ 4 ] [Yuan, Yao-Feng]Fuzhou Univ, Dept Chem, Fuzhou 350108, Fujian, Peoples R China
[ 5 ] [Xu, Feng-Bo]Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[ 6 ] [Yuan, Yao-Feng]Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[ 7 ] [Yuan, Yao-Feng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address：

袁耀锋
[Yuan, Yao-Feng]Fuzhou Univ, Dept Chem, Qi Shan Campus,2 Xue Yuan Rd, Fuzhou 350108, Fujian, Peoples R China

Email：

yaofeng_yuan@fzu.edu.cn

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Version：

Synthesis of the first 1,3-disubstituted 1,3-butadienyl heteroannular bridged [4]ferrocenophane
2011，Journal of Organometallic Chemistry
Synthesis of the first 1,3-disubstituted 1,3-butadienyl heteroannular bridged [4]ferrocenophane
2011，Journal of Organometallic Chemistry

Related Keywords：

Stepwise iododesilylation and coupling reaction: a flexible route to 2,4-disubstituted-1H-pyrroles
2016，TETRAHEDRON LETTERS

Source ：

JOURNAL OF ORGANOMETALLIC CHEMISTRY

ISSN： 0022-328X

Year： 2011

Issue： 8

Volume： 696

Page： 1491-1495

2 . 3 8 4

JCR@2011

2 . 1 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count： 4

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

化学学院本学院/部未明确归属的数据

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