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author:

Cheng, Shuying (Cheng, Shuying.) [1] (Scholars:程树英) | He, Yingjie (He, Yingjie.) [2] | Chen, Guonan (Chen, Guonan.) [3] (Scholars:陈国南)

Indexed by:

EI Scopus SCIE

Abstract:

SnS thin films were deposited onto indium tin oxide (ITO) glass substrates by constant potential cathodic electro-deposition from aqueous solution containing stannous sulfate, ethylenediamine tetraacetate acid and sodium thiosulfate. The co-deposited potential was explored by cyclic voltammetry and the deposition potential (E) was roughly determined to be more negative than -0.70 V (vs. saturated calomel electrode, SCE). The analysis of the composition of the as-deposited films by X-ray fluorescence spectrometer indicated that stoichiometric SnS films could be obtained under the condition of E = -0.95 to -1.00 V. The films deposited at E = -1.00 V were characterized with X-ray diffraction (XRD), scanning electron microscope (SEM), and their transmission and reflectance spectra were measured. The as-deposited films were polycrystalline SnS compound with orthorhombic crystalline structure and the ratio of Sn and S was nearly 1. The films were uniform and compact with small grains. The direct band gap of the films was estimated to be about 1.10-1.43 eV with an absorption coefficient near the fundamental absorption edge larger than 4 x 10(4) cm(-1). (C) 2008 Elsevier B.V. All rights reserved.

Keyword:

cyclic voltammetry EDTA electro-deposition SnS thin films

Community:

  • [ 1 ] [Cheng, Shuying]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Analyt & Detect Tech Food Safety, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [He, Yingjie]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Analyt & Detect Tech Food Safety, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Chen, Guonan]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Analyt & Detect Tech Food Safety, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Cheng, Shuying]Fuzhou Univ, Dept Elect Sci & Appl Phys, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 陈国南

    [Chen, Guonan]Fuzhou Univ, Dept Chem, Minist Educ, Key Lab Analyt & Detect Tech Food Safety, Fuzhou 350002, Fujian, Peoples R China

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Source :

MATERIALS CHEMISTRY AND PHYSICS

ISSN: 0254-0584

Year: 2008

Issue: 2-3

Volume: 110

Page: 449-453

1 . 7 9 9

JCR@2008

4 . 3 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 35

SCOPUS Cited Count: 36

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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