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SnS thin films were deposited onto indium tin oxide (ITO) glass substrates by constant potential cathodic electro-deposition from aqueous solution containing stannous sulfate, ethylenediamine tetraacetate acid and sodium thiosulfate. The co-deposited potential was explored by cyclic voltammetry and the deposition potential (E) was roughly determined to be more negative than -0.70 V (vs. saturated calomel electrode, SCE). The analysis of the composition of the as-deposited films by X-ray fluorescence spectrometer indicated that stoichiometric SnS films could be obtained under the condition of E = -0.95 to -1.00 V. The films deposited at E = -1.00 V were characterized with X-ray diffraction (XRD), scanning electron microscope (SEM), and their transmission and reflectance spectra were measured. The as-deposited films were polycrystalline SnS compound with orthorhombic crystalline structure and the ratio of Sn and S was nearly 1. The films were uniform and compact with small grains. The direct band gap of the films was estimated to be about 1.10-1.43 eV with an absorption coefficient near the fundamental absorption edge larger than 4 x 10(4) cm(-1). (C) 2008 Elsevier B.V. All rights reserved.
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MATERIALS CHEMISTRY AND PHYSICS
ISSN: 0254-0584
Year: 2008
Issue: 2-3
Volume: 110
Page: 449-453
1 . 7 9 9
JCR@2008
4 . 3 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
JCR Journal Grade:2
Cited Count:
WoS CC Cited Count: 35
SCOPUS Cited Count: 36
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1