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Abstract:
A sol-gel process catalyzed by oxalic acid was used for the preparation of SIC precursor from raw materials of letraethyl orthosilicate (TEOS) and sucrose. The precursor thus obtained was homogeneous. Sintered with a certain heating program in an argon flow, the precursor was converted into the high surface area SIC. The high specific surface. area silicon carbide was used as catalyst support for ammonia synthesis. The effect of the surface of the support, promoter and the amount of Ru on the catalytic activity for ammonia synthesis was studied. The results show that when the high specific surface area SIC of 113 m(2).g(-1) is used as support, the prepared SiC-supported ruthenium catalyst has a relatively high activity (11.85%) under Ru 4wt%, Ba 4wt%, K 8wt%, 475 degrees C, 10.0 Wa and 10000 h(-1).
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CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN: 1001-4861
CN: 32-1185/O6
Year: 2008
Issue: 6
Volume: 24
Page: 1007-1011
0 . 5 3 2
JCR@2008
0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
Cited Count:
WoS CC Cited Count: 6
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: