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author:

Zheng Yong (Zheng Yong.) [1] (Scholars:郑勇) | Zheng Ying (Zheng Ying.) [2] | Yu Wei-Peng (Yu Wei-Peng.) [3] | Wang Rong (Wang Rong.) [4] (Scholars:王榕) | Wei Ke-Mei (Wei Ke-Mei.) [5]

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

A sol-gel process catalyzed by oxalic acid was used for the preparation of SIC precursor from raw materials of letraethyl orthosilicate (TEOS) and sucrose. The precursor thus obtained was homogeneous. Sintered with a certain heating program in an argon flow, the precursor was converted into the high surface area SIC. The high specific surface. area silicon carbide was used as catalyst support for ammonia synthesis. The effect of the surface of the support, promoter and the amount of Ru on the catalytic activity for ammonia synthesis was studied. The results show that when the high specific surface area SIC of 113 m(2).g(-1) is used as support, the prepared SiC-supported ruthenium catalyst has a relatively high activity (11.85%) under Ru 4wt%, Ba 4wt%, K 8wt%, 475 degrees C, 10.0 Wa and 10000 h(-1).

Keyword:

ammonia synthesis carbothermal high specific surface area silicon carbide

Community:

  • [ 1 ] [Zheng Yong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 2 ] [Zheng Ying]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 3 ] [Wang Rong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 4 ] [Wei Ke-Mei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 5 ] [Zheng Ying]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China
  • [ 6 ] [Yu Wei-Peng]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China

Reprint 's Address:

  • 魏可镁

    [Wei Ke-Mei]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF INORGANIC CHEMISTRY

ISSN: 1001-4861

CN: 32-1185/O6

Year: 2008

Issue: 6

Volume: 24

Page: 1007-1011

0 . 5 3 2

JCR@2008

0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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