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author:

Zhang, Guoxiang (Zhang, Guoxiang.) [1] | Chen, Xiaohui (Chen, Xiaohui.) [2] (Scholars:陈晓晖)

Indexed by:

EI PKU CSCD

Abstract:

Carbon monoxide is widely present in coal-fired flue gas and automobile exhaust. The catalytic reduction of NO by incompletely-burned CO can simultaneously remove NO and CO. The catalyst plays a decisive role in the process. In this paper, the recent research results of CO catalytic reduction of NO under oxygen are reviewed systematically. The catalyst preparation method, doping modification and reaction conditions of Pd based, Ir based, Cu based, other precious metals and metal oxide catalysts are analyzed. The effects of O2 concentration, H2O and SO2 on the catalytic reaction are also investigated. The active sites and catalytic mechanism of different catalysts are summarized and compared. The inhibition mechanism of O2 in the catalytic reduction process was proposed, and the catalytic activity sequence of these kinds of catalysts was obtained. Finally, the research directions of further study are given as the inhibition mechanism of O2, reducing the use of precious metals, and adding active additives. © 2018, Chemical Industry Press. All right reserved.

Keyword:

Additives Carbon monoxide Catalysis Catalyst activity Catalysts Flue gases Nitric oxide Oxygen Precious metals Reduction

Community:

  • [ 1 ] [Zhang, Guoxiang]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 2 ] [Zhang, Guoxiang]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 3 ] [Chen, Xiaohui]School of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 4 ] [Chen, Xiaohui]National Engineering Research Center of Chemical Fertilizer Catalysts, Fuzhou University, Fuzhou; Fujian; 350002, China

Reprint 's Address:

  • 陈晓晖

    [chen, xiaohui]national engineering research center of chemical fertilizer catalysts, fuzhou university, fuzhou; fujian; 350002, china;;[chen, xiaohui]school of chemical engineering, fuzhou university, fuzhou; fujian; 350116, china

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Source :

Chemical Industry and Engineering Progress

ISSN: 1000-6613

Year: 2018

Issue: 12

Volume: 37

Page: 4654-4661

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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