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Magnetic Fe3O4 and NiCo2O4 nanoparticles were used as core materials. The ZnS shell layer is synthesized with zinc acetate and thiourea as precursors by a solvothermal process. NiCo2O4@ZnS and Fe3O4@ZnS core-shell nanoparticles were used as hydrogen production photocatalysts, which can be recycled by magnetic force for repeated hydrogen generation. The morphology, crystalline property, magnetic property, photocatalytic activity, and magnetic separation capability of the core-shell photocatalysts were studied. Fe3O4@ZnS core-shell nanoparticles exhibit better magnetic separation capability than the NiCo2O4@ZnS analog. The optimized photocatalytic hydrogen production rates of NiCo2O4@ZnS and Fe3O4@ZnS core-shell nanoparticles reach 880 μmol h-1 g-1 and 3900 μmol h-1 g- 1, respectively. Both photocatalysts can be recycled by magnetic force. Recycled photocatalysts exhibit good hydrogen generation performance after being recycled for three times. © (2014) by the Committee of WHEC2014.
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Year: 2014
Volume: 2
Page: 1297-1304
Language: English
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WoS CC Cited Count: 0
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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