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author:

Xie, Yonghui (Xie, Yonghui.) [1] | Cao, Jiaqi (Cao, Jiaqi.) [2] | Wang, Xinghui (Wang, Xinghui.) [3] (Scholars:王星辉) | Li, Wangyang (Li, Wangyang.) [4] | Deng, Liying (Deng, Liying.) [5] | Ma, Shun (Ma, Shun.) [6] | Zhang, Hong (Zhang, Hong.) [7] (Scholars:张红) | Guan, Cao (Guan, Cao.) [8] | Huang, Wei (Huang, Wei.) [9]

Indexed by:

EI SCIE

Abstract:

Lithium-sulfur batteries possess the merits of low cost and high theoretical energy density but suffer from the shuttle effect of lithium polysulfides and slow redox kinetics of sulfur. Herein, novel Co0.85Se nanoparticles embedded in nitrogen-doped carbon nanosheet arrays (Co0.85Se/NC) were constructed on carbon cloth as the self-supported host for a sulfur cathode using a facile fabrication strategy. The interconnected porous carbonbased structure of the Co0.85Se/NC could facilitate the rapid electron and ion transfer kinetics. The embedded Co0.85Se nanoparticles can effectively capture and catalyze lithium polysulfides, thus accelerating the redox kinetics and stabilizing sulfur cathodes. Therefore, the Co0.85Se/NC-S cathode could maintain a stable cycle performance for 400 cycles at 1C and deliver a high discharge specific capacity of 1361, 1001, and 810 mAh g(-1) at current densities of 0.1, 1, and 3C, respectively. This work provides an efficient design strategy for high-performance lithium-sulfur batteries with high energy densities.

Keyword:

Li-S batteries lithium polysulfides metal-organic frameworks metal selenide sulfur cathode

Community:

  • [ 1 ] [Xie, Yonghui]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices & Solar Cells, Fuzhou 350108, Peoples R China
  • [ 2 ] [Cao, Jiaqi]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices & Solar Cells, Fuzhou 350108, Peoples R China
  • [ 3 ] [Wang, Xinghui]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices & Solar Cells, Fuzhou 350108, Peoples R China
  • [ 4 ] [Li, Wangyang]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices & Solar Cells, Fuzhou 350108, Peoples R China
  • [ 5 ] [Deng, Liying]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices & Solar Cells, Fuzhou 350108, Peoples R China
  • [ 6 ] [Ma, Shun]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices & Solar Cells, Fuzhou 350108, Peoples R China
  • [ 7 ] [Zhang, Hong]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices & Solar Cells, Fuzhou 350108, Peoples R China
  • [ 8 ] [Wang, Xinghui]Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Wang, Xinghui]Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213000, Peoples R China
  • [ 10 ] [Guan, Cao]Northwestern Polytech Univ, Inst Flexible Elect, Xian Key Lab Flexible Elect, Xian 710072, Peoples R China
  • [ 11 ] [Huang, Wei]Northwestern Polytech Univ, Inst Flexible Elect, Xian Key Lab Flexible Elect, Xian 710072, Peoples R China

Reprint 's Address:

  • 王星辉

    [Wang, Xinghui]Fuzhou Univ, Coll Phys & Informat Engn, Inst Micronano Devices & Solar Cells, Fuzhou 350108, Peoples R China;;[Wang, Xinghui]Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China;;[Wang, Xinghui]Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213000, Peoples R China;;[Guan, Cao]Northwestern Polytech Univ, Inst Flexible Elect, Xian Key Lab Flexible Elect, Xian 710072, Peoples R China

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Source :

NANO LETTERS

ISSN: 1530-6984

Year: 2021

Issue: 20

Volume: 21

Page: 8579-8586

1 2 . 2 6 2

JCR@2021

9 . 6 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 169

SCOPUS Cited Count: 172

ESI Highly Cited Papers on the List: 11 Unfold All

  • 2025-1
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  • 2024-3
  • 2024-1
  • 2023-11
  • 2023-9
  • 2023-5
  • 2023-3

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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