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author:

Hao, Gu (Hao, Gu.) [1] | Shan-Ci, Chen (Shan-Ci, Chen.) [2] | Qing-Dong, Zheng (Qing-Dong, Zheng.) [3]

Indexed by:

SCIE CSCD

Abstract:

A two-dimensional (2D) organic-inorganic hybrid perovskite (OIHP) material is considered as a promising candidate for a long-term stable photodetector owing to its outstanding phase and environmental stability. Herein, we demonstrate a perovskite photodiode based on the DJ phase 2D perovskite (PDA)(MA)(n-1)PbnI3n+1 (where PDA is 1,3-propylenediamine, MA is methylamine, nominal n = 4). The best-performance device exhibits a high detectivity of 4.57 X 10(11) Jones, a responsivity of 0.25 A.W-1 at 480 nm, a low dark current density of 9.60 X 10(-4) mA.cm(-2), and a remarkable on/off ratio of 3.10 X 10(5). The unencapsulated device can maintain 95% of the initial photocurrent density after 90 days under an ambient atmosphere with relative humidity (RH) of 65%, demonstrating its improved stability than the 3D counterpart. The excellent stability of the photodiode based on 2D perovskite promises its bright commercial application future.

Keyword:

Dion-Jacobson on/off ratio photodiode stability two-dimensional perovskite

Community:

  • [ 1 ] [Hao, Gu]Fuzhou Univ, Coll Chem, Fuzhou 350000, Peoples R China
  • [ 2 ] [Hao, Gu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 3 ] [Shan-Ci, Chen]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 4 ] [Qing-Dong, Zheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Shan-Ci, Chen]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Qing-Dong, Zheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2021

Issue: 12

Volume: 40

Page: 1621-1630

0 . 8 4 7

JCR@2021

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:4

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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