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Abstract:
A two-dimensional (2D) organic-inorganic hybrid perovskite (OIHP) material is considered as a promising candidate for a long-term stable photodetector owing to its outstanding phase and environmental stability. Herein, we demonstrate a perovskite photodiode based on the DJ phase 2D perovskite (PDA)(MA)(n-1)PbnI3n+1 (where PDA is 1,3-propylenediamine, MA is methylamine, nominal n = 4). The best-performance device exhibits a high detectivity of 4.57 X 10(11) Jones, a responsivity of 0.25 A.W-1 at 480 nm, a low dark current density of 9.60 X 10(-4) mA.cm(-2), and a remarkable on/off ratio of 3.10 X 10(5). The unencapsulated device can maintain 95% of the initial photocurrent density after 90 days under an ambient atmosphere with relative humidity (RH) of 65%, demonstrating its improved stability than the 3D counterpart. The excellent stability of the photodiode based on 2D perovskite promises its bright commercial application future.
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Source :
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2021
Issue: 12
Volume: 40
Page: 1621-1630
0 . 8 4 7
JCR@2021
5 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:4
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 10
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: