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Abstract:
A portable sensor using the height of the liquid column in capillary as readout was designed for detection of hydrogen sulfide (H2S). Cuprous ion (Cu+ ) could induce the combination of azide-modified magnetic beads (MBs-N3) and alkyne-modified platinum nanoparticles ( Pt NPs-Alk) through click chemistry to form platinum nanoparticles connected to magnetic beads (MBs-Pt NPs). MBs-Pt NPs could be separated from the reaction mixture by magnetic force and transferred to a glass bottle filled with hydrogen peroxide (H2O2) solution with a capillary on bottle cap. In the above-mentioned closed reaction device, H2O2 was catalytically decomposed by Pt NPs and generated a large amount of oxygen, which caused the liquid column in the capillary to rise. In the presence of H2S, the azide groups on the surface of MBs-N3 could be reduced to amino groups by H2S, thereby reducing the click chemistry reaction sites between it and Pt NPs-Alk, ultimately leading to a reduction in the catalytic efficiency of H2O2 decomposition and a reduction in the rising height of the capillary liquid column. The change of height of the liquid column in the capillary had a linear relationship with H2S concentration in the range of 2. 0 to 60 mu mol/ L, and the limit of detection was 1. 9 mu mol/ L. The method was used for the rapid and simple determination of H2S in red wine with satisfactory results.
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CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
ISSN: 0253-3820
CN: 22-1125/O6
Year: 2022
Issue: 11
Volume: 50
Page: 1733-1742
1 . 2
JCR@2022
1 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:74
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2