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author:

Li, Zhi-Xin (Li, Zhi-Xin.) [1] | Chen, Shu-Ting (Chen, Shu-Ting.) [2] | Luo, Fang (Luo, Fang.) [3] (Scholars:罗芳) | Lin, Zhen-Yu (Lin, Zhen-Yu.) [4] (Scholars:林振宇)

Indexed by:

SCIE PKU CSCD

Abstract:

A portable sensor using the height of the liquid column in capillary as readout was designed for detection of hydrogen sulfide (H2S). Cuprous ion (Cu+ ) could induce the combination of azide-modified magnetic beads (MBs-N3) and alkyne-modified platinum nanoparticles ( Pt NPs-Alk) through click chemistry to form platinum nanoparticles connected to magnetic beads (MBs-Pt NPs). MBs-Pt NPs could be separated from the reaction mixture by magnetic force and transferred to a glass bottle filled with hydrogen peroxide (H2O2) solution with a capillary on bottle cap. In the above-mentioned closed reaction device, H2O2 was catalytically decomposed by Pt NPs and generated a large amount of oxygen, which caused the liquid column in the capillary to rise. In the presence of H2S, the azide groups on the surface of MBs-N3 could be reduced to amino groups by H2S, thereby reducing the click chemistry reaction sites between it and Pt NPs-Alk, ultimately leading to a reduction in the catalytic efficiency of H2O2 decomposition and a reduction in the rising height of the capillary liquid column. The change of height of the liquid column in the capillary had a linear relationship with H2S concentration in the range of 2. 0 to 60 mu mol/ L, and the limit of detection was 1. 9 mu mol/ L. The method was used for the rapid and simple determination of H2S in red wine with satisfactory results.

Keyword:

Capillary Click chemistry Hydrogen sulfide Liquid column height Portable sensor

Community:

  • [ 1 ] [Li, Zhi-Xin]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Anal & Detect Food Safety, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350116, Peoples R China
  • [ 2 ] [Lin, Zhen-Yu]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Anal & Detect Food Safety, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350116, Peoples R China
  • [ 3 ] [Chen, Shu-Ting]Fuzhou Univ, Coll Biol Sci & Engn, Fuzhou 350116, Peoples R China

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Source :

CHINESE JOURNAL OF ANALYTICAL CHEMISTRY

ISSN: 0253-3820

CN: 22-1125/O6

Year: 2022

Issue: 11

Volume: 50

Page: 1733-1742

1 . 2

JCR@2022

1 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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