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author:

Zhou, Wenbo (Zhou, Wenbo.) [1] | Zhang, Renwei (Zhang, Renwei.) [2] | Yu, Shijie (Yu, Shijie.) [3] | Peng, Zexuan (Peng, Zexuan.) [4] | Zuo, Caixin (Zuo, Caixin.) [5] | Yang, Wenjuan (Yang, Wenjuan.) [6] | Li, Yafeng (Li, Yafeng.) [7] (Scholars:李亚峰) | Wei, Mingdeng (Wei, Mingdeng.) [8] (Scholars:魏明灯)

Indexed by:

EI Scopus SCIE

Abstract:

Silicon-based anodes heavily depend on the binder to preserve the unbroken electrode structure. In the present work, natural flaxseed gum (FG) is used as a binder of silicon nanoparticles (SiNPs) anode for the first time. Owing to a large number of polar groups and a rich branched structure, this material not only anchors tightly to the surface of SiNPs through bonding interactions but also formed a hydrogen bonding network structure among molecules. As a result, the FG binder can endow the silicon electrode with stable interfacial adhesion and outstanding mechanical properties. In addition, FG with a high viscosity facilitates the homogeneous dispersion of the electrode components. When FG is used as a binder, the cycling performance of the Si anode is greatly improved. After one hundred cycles at an applied current density of 1 A g-1, the electrode continues to display remarkable electrochemical properties with a significant cyclic capacity (2213 mA h g-1) and initial Coulombic efficiency (ICE) of 89.7%. FG is used as a silicon-based anode binder for lithium-ion batteries for the first time. As FG possesses abundant polar groups and branched chains, it enhances the mechanical properties of the silicon electrode and greatly improves the cycling stability of the silicon electrode. image

Keyword:

binder flaxseed gum high-branched structure lithium-ion batteries silicon-based anode

Community:

  • [ 1 ] [Zhou, Wenbo]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350116, Peoples R China
  • [ 2 ] [Zhang, Renwei]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350116, Peoples R China
  • [ 3 ] [Yu, Shijie]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350116, Peoples R China
  • [ 4 ] [Peng, Zexuan]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350116, Peoples R China
  • [ 5 ] [Zuo, Caixin]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350116, Peoples R China
  • [ 6 ] [Li, Yafeng]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350116, Peoples R China
  • [ 7 ] [Wei, Mingdeng]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350116, Peoples R China
  • [ 8 ] [Yang, Wenjuan]Hefei Univ, Sch Energy Mat & Chem Engn, Hefei 230601, Peoples R China
  • [ 9 ] [Wei, Mingdeng]Fuzhou Univ, Fujian Prov Univ, Key Lab Adv Carbon Based Funct Mat, Fuzhou 350016, Peoples R China

Reprint 's Address:

  • 李亚峰 魏明灯

    [Li, Yafeng]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350116, Peoples R China;;[Wei, Mingdeng]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350116, Peoples R China;;[Wei, Mingdeng]Fuzhou Univ, Fujian Prov Univ, Key Lab Adv Carbon Based Funct Mat, Fuzhou 350016, Peoples R China

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Source :

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ISSN: 1613-6810

Year: 2024

Issue: 36

Volume: 20

1 3 . 0 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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