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author:

Fu, Z. (Fu, Z..) [1] | Tan, J. (Tan, J..) [2] | Sun, C.-F. (Sun, C.-F..) [3] | Deng, W. (Deng, W..) [4]

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Scopus

Abstract:

Magnesium-ion batteries are promising candidates for the next-generation energy storage systems. However, their development is restricted by the shortage of advanced insertion-type positive electrodes. Hybrid-ion batteries, which combine the facile alkali metal ions extraction/insertion of the cathode with the low-cost and high-safety magnesium metal anode, can harness the individual benefits of both electrodes and achieve satisfactory electrochemical performance. We present a high-performance magnesium-potassium hybrid ion battery utilizing a magnesium-potassium hybrid ion electrolyte, a magnesium metal anode, and a Prussian blue analogue cathode. The battery exhibits a discharge voltage of up to 3.0 V and delivers a reversible specific capacity of 120 mAh/g, resulting in an impressive energy density of 360 Wh/kg (based on the cathode mass only). Moreover, the battery demonstrates exceptional cycling stability, maintaining a capacity retention rate of 96% after 500 charge–discharge cycles at a current density of 50 mA/g. The reaction mechanism and energy storage mechanism of the hybrid ion battery were studied using various electrochemical testing methods and X-ray diffraction analysis. This work may provide new ideas and inspire the effort for the advancement of superior magnesium hybrid ion batteries. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

Keyword:

Cyclic stability Energy density Hybrid ion batteries Mg metal anode Prussian blue cathode

Community:

  • [ 1 ] [Fu Z.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 2 ] [Fu Z.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 3 ] [Fu Z.]Fujian College, University of Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 4 ] [Tan J.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 5 ] [Tan J.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 6 ] [Tan J.]Fujian College, University of Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 7 ] [Sun C.-F.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 8 ] [Sun C.-F.]Fujian College, University of Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 9 ] [Deng W.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 10 ] [Deng W.]Fujian College, University of Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China

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Source :

Ionics

ISSN: 0947-7047

Year: 2024

Issue: 7

Volume: 30

Page: 4055-4062

2 . 4 0 0

JCR@2023

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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