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author:

Fu, Zhao (Fu, Zhao.) [1] | Tan, Jinshuo (Tan, Jinshuo.) [2] | Sun, Chuan-Fu (Sun, Chuan-Fu.) [3] | Deng, Wenzhuo (Deng, Wenzhuo.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

Magnesium-ion batteries are promising candidates for the next-generation energy storage systems. However, their development is restricted by the shortage of advanced insertion-type positive electrodes. Hybrid-ion batteries, which combine the facile alkali metal ions extraction/insertion of the cathode with the low-cost and high-safety magnesium metal anode, can harness the individual benefits of both electrodes and achieve satisfactory electrochemical performance. We present a high-performance magnesium-potassium hybrid ion battery utilizing a magnesium-potassium hybrid ion electrolyte, a magnesium metal anode, and a Prussian blue analogue cathode. The battery exhibits a discharge voltage of up to 3.0 V and delivers a reversible specific capacity of 120 mAh/g, resulting in an impressive energy density of 360 Wh/kg (based on the cathode mass only). Moreover, the battery demonstrates exceptional cycling stability, maintaining a capacity retention rate of 96% after 500 charge-discharge cycles at a current density of 50 mA/g. The reaction mechanism and energy storage mechanism of the hybrid ion battery were studied using various electrochemical testing methods and X-ray diffraction analysis. This work may provide new ideas and inspire the effort for the advancement of superior magnesium hybrid ion batteries.

Keyword:

Cyclic stability Energy density Hybrid ion batteries Mg metal anode Prussian blue cathode

Community:

  • [ 1 ] [Fu, Zhao]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Tan, Jinshuo]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Fu, Zhao]Chinese Acad Sci, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Tan, Jinshuo]Chinese Acad Sci, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Sun, Chuan-Fu]Chinese Acad Sci, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Deng, Wenzhuo]Chinese Acad Sci, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Fu, Zhao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Tan, Jinshuo]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Sun, Chuan-Fu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Deng, Wenzhuo]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Fu, Zhao]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 12 ] [Tan, Jinshuo]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 13 ] [Sun, Chuan-Fu]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 14 ] [Deng, Wenzhuo]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Sun, Chuan-Fu]Chinese Acad Sci, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China;;[Deng, Wenzhuo]Chinese Acad Sci, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China;;[Sun, Chuan-Fu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China;;[Deng, Wenzhuo]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China;;[Sun, Chuan-Fu]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China;;[Deng, Wenzhuo]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China;;

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Source :

IONICS

ISSN: 0947-7047

Year: 2024

Issue: 7

Volume: 30

Page: 4055-4062

2 . 4 0 0

JCR@2023

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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