In　this　study,　a　novel　concept　of　multipoint　anionic　bridge　(MAB)　is　proposed　and　proved,　which　utilizes　anions　with　different　sites　to　connect　with　the　asymmetric　solvation　structure　(ASS).　Compared　to　usual　solvation　structures,　this　study　utilizes　the　multifunctional　groups　of　difluoro(oxalate)borate　anion　(ODFB-),　which　can　connect　with　Li+.　By　tailoring　the　concentration,　the　anion　serves　as　a　bridge　between　different　solvated　structures.　The　electrolyte　is　investigated　through　in　situ　techniques　and　simulations　to　draw　correlations　between　different　solvation　structures　and　reaction　pathways.　The　proposed　design　demonstrates　remarkable　high-temperature　performance　on　both　the　anode　and　cathode　sides,　enabling　stable　cycling　of　LCO||graphite　(0.5　Ah,　1.0　C)　pouch　cell　for　over　200　cycles　at　80　degrees　C　and　facilitating　Li||MCMB　and　Li||LFP　cells　to　deliver　stable　performance　for　200　cycles　at　100　degrees　C.　This　work　paves　the　way　for　the　development　of　high-performance　electrolyte　systems　by　designing　and　using　new　multipoint　anions　to　construct　ASSs.