Login | Cas Login
English| 简体中文| 繁体中文

  • Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

Advanced Search

author：

Zheng, T. (Zheng, T..) [1] | Xu, T. (Xu, T..) [2] | Xiong, J. (Xiong, J..) [3] | Xie, W. (Xie, W..) [4] | Wu, M. (Wu, M..) [5] | Yu, Y. (Yu, Y..) [6] | Xu, Z. (Xu, Z..) [7] | Liang, Y. (Liang, Y..) [8] | Liao, C. (Liao, C..) [9] | Dong, X. (Dong, X..) [10] | Xia, Y. (Xia, Y..) [11] | Cheng, Y.-J. (Cheng, Y.-J..) [12] | Müller-Buschbaum, P. (Müller-Buschbaum, P..) [14]

Indexed by：

Scopus

Abstract：

In　this　study,　a　novel　concept　of　multipoint　anionic　bridge　(MAB)　is　proposed　and　proved,　which　utilizes　anions　with　different　sites　to　connect　with　the　asymmetric　solvation　structure　(ASS).　Compared　to　usual　solvation　structures,　this　study　utilizes　the　multifunctional　groups　of　difluoro(oxalate)borate　anion　(ODFB−),　which　can　connect　with　Li+.　By　tailoring　the　concentration,　the　anion　serves　as　a　bridge　between　different　solvated　structures.　The　electrolyte　is　investigated　through　in　situ　techniques　and　simulations　to　draw　correlations　between　different　solvation　structures　and　reaction　pathways.　The　proposed　design　demonstrates　remarkable　high-temperature　performance　on　both　the　anode　and　cathode　sides,　enabling　stable　cycling　of　LCO||graphite　(0.5　Ah,　1.0　C)　pouch　cell　for　over　200　cycles　at　80 °C　and　facilitating　Li||MCMB　and　Li||LFP　cells　to　deliver　stable　performance　for　200　cycles　at　100 °C.　This　work　paves　the　way　for　the　development　of　high-performance　electrolyte　systems　by　designing　and　using　new　multipoint　anions　to　construct　ASSs.　©　2024　The　Author(s).　Advanced　Science　published　by　Wiley-VCH　GmbH.

Keyword：

asymmetric solvation structure high-concentration electrolyte high temperature lithium difluoro(oxalate)borate lithium metal batteries

Community：

  • [ 1 ] [Zheng T.]Chair for Functional Materials, Department of Physics, TUM School of Natural Sciences, Technical University of Munich, James-Franck-Str. 1, Garching, 85748, Germany
  • [ 2 ] [Xu T.]Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 1219 Zhongguan West Rd, Zhejiang, Ningbo, 315201, China
  • [ 3 ] [Xu T.]Department of Chemistry, College of Sciences, Shanghai University, Shanghai, 200444, China
  • [ 4 ] [Xiong J.]College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China
  • [ 5 ] [Xie W.]Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 1219 Zhongguan West Rd, Zhejiang, Ningbo, 315201, China
  • [ 6 ] [Wu M.]Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 1219 Zhongguan West Rd, Zhejiang, Ningbo, 315201, China
  • [ 7 ] [Yu Y.]AIE Institute, Guangdong, 510530, China
  • [ 8 ] [Xu Z.]Chair for Functional Materials, Department of Physics, TUM School of Natural Sciences, Technical University of Munich, James-Franck-Str. 1, Garching, 85748, Germany
  • [ 9 ] [Liang Y.]Chair for Functional Materials, Department of Physics, TUM School of Natural Sciences, Technical University of Munich, James-Franck-Str. 1, Garching, 85748, Germany
  • [ 10 ] [Liao C.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 11 ] [Dong X.]Department of Chemistry, Institute of New Energy, Fudan University, Shanghai, 200433, China
  • [ 12 ] [Xia Y.]College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China
  • [ 13 ] [Xia Y.]Department of Chemistry, Institute of New Energy, Fudan University, Shanghai, 200433, China
  • [ 14 ] [Cheng Y.-J.]Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 1219 Zhongguan West Rd, Zhejiang, Ningbo, 315201, China
  • [ 15 ] [Cheng Y.-J.]College of Renewable Energy, Hohai University, Jiangsu, 213220, China
  • [ 16 ] [Xia Y.]Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 1219 Zhongguan West Rd, Zhejiang, Ningbo, 315201, China
  • [ 17 ] [Xia Y.]Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China
  • [ 18 ] [Müller-Buschbaum P.]Chair for Functional Materials, Department of Physics, TUM School of Natural Sciences, Technical University of Munich, James-Franck-Str. 1, Garching, 85748, Germany

Reprint 's Address：

Email：

Show more details

Related Keywords：

Related Article：

Source ：

Advanced Science

ISSN： 2198-3844

Year： 2024

Issue： 48

Volume： 11

1 4 . 3 0 0

JCR@2023

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 2

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS
Online/Total：462/10786052
Address：FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code：350116) Contact Us：0591-22865326
Copyright：FZU Library Technical Support：Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1