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author:

Wei, X. (Wei, X..) [1] | Lv, X. (Lv, X..) [2] | Cui, A. (Cui, A..) [3] | Zhao, C. (Zhao, C..) [4] | Ma, Y. (Ma, Y..) [5] | Zhang, X.-X. (Zhang, X.-X..) [6] | Yuan, Y. (Yuan, Y..) [7] | Wu, J. (Wu, J..) [8]

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Scopus

Abstract:

For environmentally benign lead-free ferroelectric ceramics, the trait of temperature-dependent phase boundary renders ceramics with intrinsic temperature sensitivity, obstructing them toward practical applications. Recently, laminated composite ceramics were widely implemented to solve temperature instability. However, such 2-2 type structure exhibits inherent limitations on properties promotion. Given this, the present work proposes a novel strategy of 3-3-like heterostructure engineering to tackle the problem. Compared to the laminated counterpart, 3-3-like ceramic shows boosted dielectric, ferroelectric and strain properties. Significantly, its electrocaloric (EC) operating range is expanded from 18 to 49 °C, two-fold wider than the laminated one, while a large EC temperature change of 0.66 K@30 kV/cm is maintained, which shows great property advantages to that of state-of-art lead-free ceramics. The superior performance benefits from the relatively uniform field dispersion of 3-3-like heterogeneity. As a contrast, sharp interface divergence causes abnormal field distribution and phase destabilization in laminated structure, which undermines the electrical properties and limits temperature stability. This work offers a favorable strategy for designing high-performance lead-free materials with desirable temperature reliability. © 2024

Keyword:

3-3-like Barium titanate Heterostructure engineering Lead-free Temperature stability

Community:

  • [ 1 ] [Wei X.]College of Materials Science and Engineering, Sichuan University, Chengdu, 610065, China
  • [ 2 ] [Lv X.]College of Materials Science and Engineering, Sichuan University, Chengdu, 610065, China
  • [ 3 ] [Cui A.]Key Laboratory of Optoelectronic Material and Device, Department of Physics, Shanghai Normal University, Shanghai, 200234, China
  • [ 4 ] [Zhao C.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Ma Y.]Division of Physical Science and Engineering, King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia
  • [ 6 ] [Zhang X.-X.]Division of Physical Science and Engineering, King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia
  • [ 7 ] [Yuan Y.]Core Labs, King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia
  • [ 8 ] [Wu J.]College of Materials Science and Engineering, Sichuan University, Chengdu, 610065, China
  • [ 9 ] [Wu J.]College of Physics, Sichuan University, Chengdu, 610064, China

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Source :

Acta Materialia

ISSN: 1359-6454

Year: 2025

Volume: 285

8 . 3 0 0

JCR@2023

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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